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Merck KGaA reactants and solvents
Reactants And Solvents, supplied by Merck KGaA, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/reactants/reactants+reagents/pmc11435393-314-2-12
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reactants and solvents - by Bioz Stars, 2026-10
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Distillation:

Article Title: [Benzylamine-K2-C,N]1,2-Bis (Diphenylphosphino)-Propane-k2-P,P] Palladium}Perchlorate, Mononuclear Complex of Ortho-Palladated Derived from Benzylamine
Article Snippet: This work reports the preparation of the mononuclear derivative [Pd(C6H4CH2NH2) L](ClO4) (L = dppp).. The centrosymmetric mononuclear palladium complex obtained by the reaction of palladium(II) acetate with benzylamine in toluene produced the acetate cyclopalladated dimer of benzylamine.. Metathesis reaction of this acetate-bridged cyclopalladated complex with NaCl in water and acetone gave N,C-orthopalladated [Pd(C6H4CH2NH2)(l-Cl)]2 complex, which reacts with NaClO4/ dppp to give the mononuclear derivative.

Article Title: Novel Pyrrole Derivatives as Multi-Target Agents for the Treatment of Alzheimer’s Disease: Microwave-Assisted Synthesis, In Silico Studies and Biological Evaluation
Article Snippet: Reactants and solvents were obtained from commercial suppliers (Sigma Aldrih and Acros, Merck KGaA, Darmstadt, Germany), and used without further purification.

Article Title: Hydrogen-Bonding-Driven Design of Organic-Inorganic Hybrid Ferroelastics with Reversible Photoisomerization.
Article Snippet: The development of photoresponsive ferroelastics, which couple light-induced macroscopic mechanical and microscopic domain properties, represents a frontier in materials science with profound implications for advanced functional applications.. In this study, we report the rational design and synthesis of two new organic−inorganic hybrid ferroelastic crystals, (MA)(Me4N)[Fe(CN)5(NO)] (MA = methylammonium) (1) and (MA)(Me3NOH)[Fe(CN)5(NO)] (2), using a dual-organic molecular design strategy that exploits hydrogen-bonding interactions for tailoring ferroelastic properties.. Specifically, 1 exhibits a two-step phase transition at 138 and 242 K, while the introduction of a hydroxyl group in 2 stabilizes its ferroelastic phase to a significantly higher temperature, achieving a phase transition at 328 K, 86 K above that of 1.

Article Title: Biomarkers in Community-Acquired Pneumonia Assessment
Article Snippet: Chemically pure reactants (analytical grade) from Merck (Darmstadt, Germany), H2O2 from Sigma-Aldrich (St. Luis, USA) were used; water was double distilled (distillation apparatus from Sanyo Gallenkamp PLC, Leicester, UK).

Article Title: Peculiarities in thermal evolution of precipitated amorphous calcium phosphates with an initial Ca/P ratio of 1:1.
Article Snippet: Thermal evolution of amorphous calcium phosphate (ACP) powder from a fast nitrate synthesis with a Ca/ P ratio of 1:1 were studied in the range of 20–980 °C.. The powder consisted of amorphous dicalcium phosphate anhydrate (CaHPO4) after heating to 200 °C.. CaHPO4 gradually condensed to amorphous calcium pyrophosphate Ca2P2O7 (CPP) between 200 to 620 °C.

Article Title: Highly efficacious preparation of 3,3′-(arylmethylene)-bis(2-hydroxynaphthoquinone) derivatives catalyzed by a nanorod-structured organic–inorganic hybrid material
Article Snippet: A nanorod-structured organic–inorganic hybrid material namely nanorod-[SiO2– Pr–Im–SO3H][CF3CO2] (N-[SPIS][TFA]) has been applied as a highly efficacious, dual-functional, and recoverable catalyst for the solvent-free preparation of 3,3’-(arylmethylene)-bis(2-hydroxynaphthoquinone) {3,3′-(arylmethylene)-bis(2hydroxynaphthalene-1,4-dione)} derivatives in high yields and relatively short times.. The one-pot pseudo-multi-component reaction of 2-hydroxynaphthoquinone (2-hydroxynaphthalene-1,4-dione) (2 eq.) and arylaldehydes (1 eq.) has been used for the preparation of these compounds.. Graphic abstract

Article Title: Synthesis and characterization of new derivatives of bis(1,4‐diazepinium) salts and bis(γ‐substituted pentamethine cyanine(dyes using vinamidinium salt
Article Snippet: Correspondence Abdolmohammad Mehranpour, Department of Chemistry, Faculty of Science, Persian Gulf University, Bushehr 75169, Iran.. Email: ammehranpour@hotmail.com Abstract The preparation of several bis(1,4-diazepinium) salts from the reaction of three 1,2-diamines with a bis(vinamidinium) salt is described.. Bis(γ-substituted pentamethine cyanine(dyes are also prepared from the reaction of vinamidinium salt with 1,2-dimethylquinolinium perchlorate and 1,2,3,3-tetramethyl-3Hindolium perchlorate.

Article Title: Functionalized and oxidized silicon nanosheets: Customized design for enhanced sensitivity towards relative humidity
Article Snippet: Accepted Manuscript Title: Functionalized and Oxidized Silicon Nanosheets: Customized Design for Enhanced Sensitivity towards Relative Humidity Authors: Alina Lyuleeva, Tobias Helbich, Marco Bobinger, Bernhard Rieger, Markus Becherer, Paolo Lugli, Almudena Rivadeneyra PII: S0925-4005(18)32003-3 DOI: https://doi.org/10.1016/j.snb.2018.11.049 Reference: SNB 25647 To appear in: Sensors and Actuators B Received date: 24 June 2018 Revised date: 16 October 2018 Accepted date: 8 November 2018 Please cite this article as: Lyuleeva A, Helbich T, Bobinger M, Rieger B, Becherer M, Lugli P, Rivadeneyra A, Functionalized and Oxidized Silicon Nanosheets: Customized Design for Enhanced Sensitivity towards Relative Humidity, Sensors and amp; Actuators: B.. Chemical (2018), https://doi.org/10.1016/j.snb.2018.11.049 This is a PDF file of an unedited manuscript that has been accepted for publication.. As a service to our customers we are providing this early version of the manuscript.

Planar Chromatography:

Article Title: [Benzylamine-K2-C,N]1,2-Bis (Diphenylphosphino)-Propane-k2-P,P] Palladium}Perchlorate, Mononuclear Complex of Ortho-Palladated Derived from Benzylamine
Article Snippet: This work reports the preparation of the mononuclear derivative [Pd(C6H4CH2NH2) L](ClO4) (L = dppp).. The centrosymmetric mononuclear palladium complex obtained by the reaction of palladium(II) acetate with benzylamine in toluene produced the acetate cyclopalladated dimer of benzylamine.. Metathesis reaction of this acetate-bridged cyclopalladated complex with NaCl in water and acetone gave N,C-orthopalladated [Pd(C6H4CH2NH2)(l-Cl)]2 complex, which reacts with NaClO4/ dppp to give the mononuclear derivative.

Article Title: Novel Pyrrole Derivatives as Multi-Target Agents for the Treatment of Alzheimer’s Disease: Microwave-Assisted Synthesis, In Silico Studies and Biological Evaluation
Article Snippet: Reactants and solvents were obtained from commercial suppliers (Sigma Aldrih and Acros, Merck KGaA, Darmstadt, Germany), and used without further purification.

Article Title: Hydrogen-Bonding-Driven Design of Organic-Inorganic Hybrid Ferroelastics with Reversible Photoisomerization.
Article Snippet: The development of photoresponsive ferroelastics, which couple light-induced macroscopic mechanical and microscopic domain properties, represents a frontier in materials science with profound implications for advanced functional applications.. In this study, we report the rational design and synthesis of two new organic−inorganic hybrid ferroelastic crystals, (MA)(Me4N)[Fe(CN)5(NO)] (MA = methylammonium) (1) and (MA)(Me3NOH)[Fe(CN)5(NO)] (2), using a dual-organic molecular design strategy that exploits hydrogen-bonding interactions for tailoring ferroelastic properties.. Specifically, 1 exhibits a two-step phase transition at 138 and 242 K, while the introduction of a hydroxyl group in 2 stabilizes its ferroelastic phase to a significantly higher temperature, achieving a phase transition at 328 K, 86 K above that of 1.

Article Title: Biomarkers in Community-Acquired Pneumonia Assessment
Article Snippet: Chemically pure reactants (analytical grade) from Merck (Darmstadt, Germany), H2O2 from Sigma-Aldrich (St. Luis, USA) were used; water was double distilled (distillation apparatus from Sanyo Gallenkamp PLC, Leicester, UK).

Article Title: Peculiarities in thermal evolution of precipitated amorphous calcium phosphates with an initial Ca/P ratio of 1:1.
Article Snippet: Thermal evolution of amorphous calcium phosphate (ACP) powder from a fast nitrate synthesis with a Ca/ P ratio of 1:1 were studied in the range of 20–980 °C.. The powder consisted of amorphous dicalcium phosphate anhydrate (CaHPO4) after heating to 200 °C.. CaHPO4 gradually condensed to amorphous calcium pyrophosphate Ca2P2O7 (CPP) between 200 to 620 °C.

Article Title: Highly efficacious preparation of 3,3′-(arylmethylene)-bis(2-hydroxynaphthoquinone) derivatives catalyzed by a nanorod-structured organic–inorganic hybrid material
Article Snippet: A nanorod-structured organic–inorganic hybrid material namely nanorod-[SiO2– Pr–Im–SO3H][CF3CO2] (N-[SPIS][TFA]) has been applied as a highly efficacious, dual-functional, and recoverable catalyst for the solvent-free preparation of 3,3’-(arylmethylene)-bis(2-hydroxynaphthoquinone) {3,3′-(arylmethylene)-bis(2hydroxynaphthalene-1,4-dione)} derivatives in high yields and relatively short times.. The one-pot pseudo-multi-component reaction of 2-hydroxynaphthoquinone (2-hydroxynaphthalene-1,4-dione) (2 eq.) and arylaldehydes (1 eq.) has been used for the preparation of these compounds.. Graphic abstract

Article Title: Synthesis and characterization of new derivatives of bis(1,4‐diazepinium) salts and bis(γ‐substituted pentamethine cyanine(dyes using vinamidinium salt
Article Snippet: Correspondence Abdolmohammad Mehranpour, Department of Chemistry, Faculty of Science, Persian Gulf University, Bushehr 75169, Iran.. Email: ammehranpour@hotmail.com Abstract The preparation of several bis(1,4-diazepinium) salts from the reaction of three 1,2-diamines with a bis(vinamidinium) salt is described.. Bis(γ-substituted pentamethine cyanine(dyes are also prepared from the reaction of vinamidinium salt with 1,2-dimethylquinolinium perchlorate and 1,2,3,3-tetramethyl-3Hindolium perchlorate.

Article Title: Functionalized and oxidized silicon nanosheets: Customized design for enhanced sensitivity towards relative humidity
Article Snippet: Accepted Manuscript Title: Functionalized and Oxidized Silicon Nanosheets: Customized Design for Enhanced Sensitivity towards Relative Humidity Authors: Alina Lyuleeva, Tobias Helbich, Marco Bobinger, Bernhard Rieger, Markus Becherer, Paolo Lugli, Almudena Rivadeneyra PII: S0925-4005(18)32003-3 DOI: https://doi.org/10.1016/j.snb.2018.11.049 Reference: SNB 25647 To appear in: Sensors and Actuators B Received date: 24 June 2018 Revised date: 16 October 2018 Accepted date: 8 November 2018 Please cite this article as: Lyuleeva A, Helbich T, Bobinger M, Rieger B, Becherer M, Lugli P, Rivadeneyra A, Functionalized and Oxidized Silicon Nanosheets: Customized Design for Enhanced Sensitivity towards Relative Humidity, Sensors and amp; Actuators: B.. Chemical (2018), https://doi.org/10.1016/j.snb.2018.11.049 This is a PDF file of an unedited manuscript that has been accepted for publication.. As a service to our customers we are providing this early version of the manuscript.



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