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Diffuse Reflectance Spectroscopy Drs Analysis, supplied by JASCO Inc, used in various techniques. Bioz Stars score: 99/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
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diffuse reflectance uv  (Hitachi Ltd)
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( <t>A</t> <t>)</t> <t>UV-vis-NIR</t> absorption spectra of 2D c-MOF films (self-assembled on glass-based substrates), with data normalized to the absorption peak in the NIR-II region. ( B ) Simulated absorption spectra of different molecular segments, including the small-conjugated, noncoordinated fragment without radicals (H-DAI); the small-conjugated, noncoordinated fragment with radicals (H-DAI-2H); the small-conjugated, coordinated fragment with radicals (Ni-2-H-DAI); the extended-conjugated, noncoordinated fragment without radicals (ligand, H-HATI); the extended-conjugated, noncoordinated fragment with radicals (H-HATI-2H); and the extended-conjugated and coordinated fragment with radicals (Ni-2-H-HATI). ( C ) Electron-hole distributions of H-CMOF (left) and Me-CMOF (right) corresponding to the NIR-II-related transition. ( D and E ) Effect of alkyl chains on electrostatic potential distribution (D) and molecular configuration (E) of 2D c-MOFs. ( F ) High-resolution XPS spectrum of Ni (2p) for 2D c-MOFs.
Diffuse Reflectance Uv, supplied by Hitachi Ltd, used in various techniques. Bioz Stars score: 99/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
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zeiss stereo discovery v8 microscope  (Carl Zeiss)
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( <t>A</t> <t>)</t> <t>UV-vis-NIR</t> absorption spectra of 2D c-MOF films (self-assembled on glass-based substrates), with data normalized to the absorption peak in the NIR-II region. ( B ) Simulated absorption spectra of different molecular segments, including the small-conjugated, noncoordinated fragment without radicals (H-DAI); the small-conjugated, noncoordinated fragment with radicals (H-DAI-2H); the small-conjugated, coordinated fragment with radicals (Ni-2-H-DAI); the extended-conjugated, noncoordinated fragment without radicals (ligand, H-HATI); the extended-conjugated, noncoordinated fragment with radicals (H-HATI-2H); and the extended-conjugated and coordinated fragment with radicals (Ni-2-H-HATI). ( C ) Electron-hole distributions of H-CMOF (left) and Me-CMOF (right) corresponding to the NIR-II-related transition. ( D and E ) Effect of alkyl chains on electrostatic potential distribution (D) and molecular configuration (E) of 2D c-MOFs. ( F ) High-resolution XPS spectrum of Ni (2p) for 2D c-MOFs.
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( <t>A</t> <t>)</t> <t>UV-vis-NIR</t> absorption spectra of 2D c-MOF films (self-assembled on glass-based substrates), with data normalized to the absorption peak in the NIR-II region. ( B ) Simulated absorption spectra of different molecular segments, including the small-conjugated, noncoordinated fragment without radicals (H-DAI); the small-conjugated, noncoordinated fragment with radicals (H-DAI-2H); the small-conjugated, coordinated fragment with radicals (Ni-2-H-DAI); the extended-conjugated, noncoordinated fragment without radicals (ligand, H-HATI); the extended-conjugated, noncoordinated fragment with radicals (H-HATI-2H); and the extended-conjugated and coordinated fragment with radicals (Ni-2-H-HATI). ( C ) Electron-hole distributions of H-CMOF (left) and Me-CMOF (right) corresponding to the NIR-II-related transition. ( D and E ) Effect of alkyl chains on electrostatic potential distribution (D) and molecular configuration (E) of 2D c-MOFs. ( F ) High-resolution XPS spectrum of Ni (2p) for 2D c-MOFs.
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( <t>A</t> <t>)</t> <t>UV-vis-NIR</t> absorption spectra of 2D c-MOF films (self-assembled on glass-based substrates), with data normalized to the absorption peak in the NIR-II region. ( B ) Simulated absorption spectra of different molecular segments, including the small-conjugated, noncoordinated fragment without radicals (H-DAI); the small-conjugated, noncoordinated fragment with radicals (H-DAI-2H); the small-conjugated, coordinated fragment with radicals (Ni-2-H-DAI); the extended-conjugated, noncoordinated fragment without radicals (ligand, H-HATI); the extended-conjugated, noncoordinated fragment with radicals (H-HATI-2H); and the extended-conjugated and coordinated fragment with radicals (Ni-2-H-HATI). ( C ) Electron-hole distributions of H-CMOF (left) and Me-CMOF (right) corresponding to the NIR-II-related transition. ( D and E ) Effect of alkyl chains on electrostatic potential distribution (D) and molecular configuration (E) of 2D c-MOFs. ( F ) High-resolution XPS spectrum of Ni (2p) for 2D c-MOFs.
Spectralon White Diffuse Reflectance Standard, supplied by Labsphere Inc, used in various techniques. Bioz Stars score: 86/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
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( <t>A</t> <t>)</t> <t>UV-vis-NIR</t> absorption spectra of 2D c-MOF films (self-assembled on glass-based substrates), with data normalized to the absorption peak in the NIR-II region. ( B ) Simulated absorption spectra of different molecular segments, including the small-conjugated, noncoordinated fragment without radicals (H-DAI); the small-conjugated, noncoordinated fragment with radicals (H-DAI-2H); the small-conjugated, coordinated fragment with radicals (Ni-2-H-DAI); the extended-conjugated, noncoordinated fragment without radicals (ligand, H-HATI); the extended-conjugated, noncoordinated fragment with radicals (H-HATI-2H); and the extended-conjugated and coordinated fragment with radicals (Ni-2-H-HATI). ( C ) Electron-hole distributions of H-CMOF (left) and Me-CMOF (right) corresponding to the NIR-II-related transition. ( D and E ) Effect of alkyl chains on electrostatic potential distribution (D) and molecular configuration (E) of 2D c-MOFs. ( F ) High-resolution XPS spectrum of Ni (2p) for 2D c-MOFs.
Chromameter Cr 400 Reflectance Colorimeter, supplied by Konica Minolta, used in various techniques. Bioz Stars score: 86/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
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( <t>A</t> <t>)</t> <t>UV-vis-NIR</t> absorption spectra of 2D c-MOF films (self-assembled on glass-based substrates), with data normalized to the absorption peak in the NIR-II region. ( B ) Simulated absorption spectra of different molecular segments, including the small-conjugated, noncoordinated fragment without radicals (H-DAI); the small-conjugated, noncoordinated fragment with radicals (H-DAI-2H); the small-conjugated, coordinated fragment with radicals (Ni-2-H-DAI); the extended-conjugated, noncoordinated fragment without radicals (ligand, H-HATI); the extended-conjugated, noncoordinated fragment with radicals (H-HATI-2H); and the extended-conjugated and coordinated fragment with radicals (Ni-2-H-HATI). ( C ) Electron-hole distributions of H-CMOF (left) and Me-CMOF (right) corresponding to the NIR-II-related transition. ( D and E ) Effect of alkyl chains on electrostatic potential distribution (D) and molecular configuration (E) of 2D c-MOFs. ( F ) High-resolution XPS spectrum of Ni (2p) for 2D c-MOFs.
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reflectance atr accessory  (Specac Inc)
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( <t>A</t> <t>)</t> <t>UV-vis-NIR</t> absorption spectra of 2D c-MOF films (self-assembled on glass-based substrates), with data normalized to the absorption peak in the NIR-II region. ( B ) Simulated absorption spectra of different molecular segments, including the small-conjugated, noncoordinated fragment without radicals (H-DAI); the small-conjugated, noncoordinated fragment with radicals (H-DAI-2H); the small-conjugated, coordinated fragment with radicals (Ni-2-H-DAI); the extended-conjugated, noncoordinated fragment without radicals (ligand, H-HATI); the extended-conjugated, noncoordinated fragment with radicals (H-HATI-2H); and the extended-conjugated and coordinated fragment with radicals (Ni-2-H-HATI). ( C ) Electron-hole distributions of H-CMOF (left) and Me-CMOF (right) corresponding to the NIR-II-related transition. ( D and E ) Effect of alkyl chains on electrostatic potential distribution (D) and molecular configuration (E) of 2D c-MOFs. ( F ) High-resolution XPS spectrum of Ni (2p) for 2D c-MOFs.
Reflectance Atr Accessory, supplied by Specac Inc, used in various techniques. Bioz Stars score: 86/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
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( A ) UV-vis-NIR absorption spectra of 2D c-MOF films (self-assembled on glass-based substrates), with data normalized to the absorption peak in the NIR-II region. ( B ) Simulated absorption spectra of different molecular segments, including the small-conjugated, noncoordinated fragment without radicals (H-DAI); the small-conjugated, noncoordinated fragment with radicals (H-DAI-2H); the small-conjugated, coordinated fragment with radicals (Ni-2-H-DAI); the extended-conjugated, noncoordinated fragment without radicals (ligand, H-HATI); the extended-conjugated, noncoordinated fragment with radicals (H-HATI-2H); and the extended-conjugated and coordinated fragment with radicals (Ni-2-H-HATI). ( C ) Electron-hole distributions of H-CMOF (left) and Me-CMOF (right) corresponding to the NIR-II-related transition. ( D and E ) Effect of alkyl chains on electrostatic potential distribution (D) and molecular configuration (E) of 2D c-MOFs. ( F ) High-resolution XPS spectrum of Ni (2p) for 2D c-MOFs.

Journal: Science Advances

Article Title: Super-stable two-dimensional radical conjugated metal-organic frameworks for efficient NIR-II photothermal conversion

doi: 10.1126/sciadv.aec7519

Figure Lengend Snippet: ( A ) UV-vis-NIR absorption spectra of 2D c-MOF films (self-assembled on glass-based substrates), with data normalized to the absorption peak in the NIR-II region. ( B ) Simulated absorption spectra of different molecular segments, including the small-conjugated, noncoordinated fragment without radicals (H-DAI); the small-conjugated, noncoordinated fragment with radicals (H-DAI-2H); the small-conjugated, coordinated fragment with radicals (Ni-2-H-DAI); the extended-conjugated, noncoordinated fragment without radicals (ligand, H-HATI); the extended-conjugated, noncoordinated fragment with radicals (H-HATI-2H); and the extended-conjugated and coordinated fragment with radicals (Ni-2-H-HATI). ( C ) Electron-hole distributions of H-CMOF (left) and Me-CMOF (right) corresponding to the NIR-II-related transition. ( D and E ) Effect of alkyl chains on electrostatic potential distribution (D) and molecular configuration (E) of 2D c-MOFs. ( F ) High-resolution XPS spectrum of Ni (2p) for 2D c-MOFs.

Article Snippet: The reflection spectra of 2D c-MOFs solid-state films were measured on a diffuse reflectance UV-vis-NIR absorption spectrometer (UH4150, Hitachi Co.) at the Renmin University of China Analysis Center (fig. S28A).

Techniques: